Oriekhova O. V., Kharlamova A. V., Pavlichenko O. F.
ENVIRONMENTAL AND CHEMICAL FEATURES OF WATER IN NATURAL WATER BODIES OF THE KRYVYI RIH IRON ORE BASIN
Show/Download
About the author:
Oriekhova O. V., Kharlamova A. V., Pavlichenko O. F.
Heading:
HYGIENE, ECOLOGY AND EPIDEMIOLOGY
Type of article:
Scientific article
Annotation:
Water resources of the Kryvyi Rih iron ore basin are exposed to considerable anthropogenic pressure caused by the discharge of highly mineralized mine and quarry waters, which leads to degradation of the natural water bodies. Particular attention should be paid to monitoring the chemical composition in the Inhulets, Saksahan, and Dnipro rivers, which form the regional hydrographic network and serve as important sources for economic water use. Aim is to provide a comprehensive assessment of the chemical composition and ecological status of surface waters within the Kryvyi Rih iron ore basin, using the Inhulets, Saksahan, and Dnipro rivers and the reservoirs of the city of Kryvyi Rih as case studies, with consideration of territorial and seasonal variations in mineralization, hardness, ionic composition, and organic pollution indicators. Data from the state monitoring of surface waters (2020-2023) and protocols of departmental laboratory observations (2000-2023) were used. The analysis was performed based on the following parameters: pH, hardness, total dissolved solids, chloride and sulfate concentrations, BOD₅, BOD₂₀, COD, dissolved oxygen, and nitrogen forms. Data processing was carried out using descriptive statistical methods, with comparisons among sampling sites and seasonal dynamics, relative to the maximum permissible concentrations (Order of the Ministry of Health of Ukraine No. 721, 2022). It was established that the main factor contributing to non-compliance with water quality standards is increased mineralization due to elevated concentrations of Cl⁻ and SO₄²⁻ ions, particularly in areas affected by regulated mine water discharges. Dissolved oxygen, BOD, and COD values indicate a moderate organic load, while nitrogen compounds generally comply with regulatory limits. River basins of the Inhulets and Saksahan are characterized by local areas with elevated mineralization levels, reflecting the technogenic impact of mining enterprises. Strengthening monitoring and implementing mine-water demineralization technologies are advisable to reduce ionic loading.
Tags:
Bibliography:
- Marenkov OM, Kurchenko VO, Nesterenko OS. Assessment of the quality and ecological status of the Saksagan River in the context of drinking water and fishery purposes. Journal of Chemistry and Technologies. 2023;31(4):907-916. Available from: http://chemistry.dnu.dp.ua/article/ view/291632.
- Kovrov O, Pavlychenko A, Kulikova D. Development of the wastewater treatment technology for the mine ‘Ternivska’ of the Kryvyi Rih iron ore plant. Environ Technol. 2025;46(6):908-921. DOI: 10.1080/09593330. 2024.2371080.
- Sherstiuk NP, Khilchevskyi VK, Zabokrytska MR. Environmental risk assessment of Kryvbas mine water discharges into the Inhulets River (2005–2021). Proceedings of the 17th International Conference Monitoring of Geological Processes and Ecological Condition of the Environment; 2023 Nov 7-10. Kyiv. Kyiv: European Association of Geoscientists & Engineers; 2023. p. 1-5. DOI: 10.3997/2214-4609.2023520002.
- Kovalchuk VP, Nechai OM, Balykhina HA, Voitovych OP. Estimation of water loss for total evaporation from the surface of ponds and reservoirs in the Ingulets River basin. Land Reclamation and Water Management. 2025;1:36-49.
- Shumilova O, Osadcha N, Oreshchenko A, Grossart HP. Environmental effects of the Kakhovka Dam destruction by warfare in Ukraine. Science. 2025;387(6739):1181-1186. DOI: 10.1126/science.adn8655.
- Jiang D, Khokhlov V, Tuchkovenko Y, Kushnir D, Ovcharuk V, Spyrakos E, et al. Biogeochemical response of the north-western Black Sea after the Kakhovka collapse. Commun Earth Environ. 2025;6:185. Available from: https://www.nature.com/articles/s43247-025-02153-z.
- World Bank. Renewable internal freshwater resources per capita (ER.H2O.INTR.PC). Rome: Food and Agriculture Organization of the United Nations; 2024. Available from: https://data.worldbank.org/indicator/ ER.H2O.INTR.PC.
- Our World in Data. Per-capita renewable freshwater resources (WDI/AQUASTAT). Rome: Food and Agriculture Organization of the United Nations; 2025. Available from: https://ourworldindata.org/grapher/ per-capita-renewable-freshwater-resources.
- European Environment Agency (EEA). Europe’s State of Water 2024. Copenhagen: EEA; 2024. Available from: https://www.eea.europa. eu/en/ analysis/publications/europes-state-of-water-2024.
- Ecologic Institute. Europe’s State of Water 2024: The need for improved water resilience. Berlin: Ecologic Institute; 2024. Available from: https://www.ecologic.eu/19853.
- Northern Ireland Audit Office. Water Quality in Northern Ireland’s Rivers and Lakes. Belfast: Northern Ireland Audit Office; 2024. 66 p. Available from: https://www.niauditoffice.gov.uk/files/niauditoffice/documents/2024-03/00311423%20-%20NIA9797%20-%20Water%20 Quality%20Report_% 28WEB%29_V2.pdf.
- ICPDR. Ukraine adopts nine River Basin Management Plans (2025–2030). Vienna: ICPDR; 2025. Available from: https://www.icpdr.org/.
- Kabinet Ministriv Ukrayiny. Rozporyadzhennya KMU № 1077-r Pro zatverdzhennya planiv upravlinnya richkovymy baseynamy Dnipra ta Donu na 2025–2030 roky. Kyyiv: KMU; 2024. Dostupno: . [in Ukrainian].
- Bryl A, Vasko P, Kromplyas B. Main trends and indicators of the industrial implementation of water desalination technologies (according to the materials of the scientific and practical conference Renewable Energy and Energy Efficiency in the XXI Century 2024. Kyiv. Ukraine). Vidnovluvana Energetyka. 2024;4(79):89-103. DOI: 10.36296/1819-8058.2024.4(79).89-103. Available from: https://ve.org.ua/index.php/journal/article/view/491.
- Kovrov OS, Kulikova DV. Ukraine’s Capacity to Implement the Sustainable Development Program in the Context of Full-Scale Armed Aggression. Vol. 2. Riga: Publishing House “Baltija Publishing”; 2025. Chapter, Justification of zero-liquid-discharge technologies for desalination of highly mineralized wastewater at Kryvyi Rih iron ore basin (Ukraine); p. 464-486. DOI: 10.30525/978-9934-26-570-9-41.
- Kabinet Ministriv Ukrayiny. Rozporyadzhennya № 42-r Pro skydannya nadlyshkiv zvorotnykh vod u r. Inhulets u mizhvehetatsiynyy period 2023–2024 rokiv. Kyyiv: KMU; 2024. Dostupno: https://zakon.rada.gov.ua/go/42-2024-%D1%80. [in Ukrainian].
- Kabinet Ministriv Ukrayiny. Rozporyadzhennya № 1179-r Pro zatverdzhennya obsyahiv skydiv zvorotnykh vod hirnychodobuvnykh pidpryyemstv Kryvorizkoho zalizorudnoho baseynu u 2024 rotsi. Kyyiv: KMU; 2025. Dostupno: https://zakon.rada.gov.ua/go/1179-2025- %D1%80. [in Ukrainian].
- EUWI+ Result 2. Investigative Monitoring of the Dnieper River Basin: Pollutants Screening. Vienna: EU Member State Consortium; 2021. Available from: https://euneighbourseast.eu/wp-content/uploads/ 2021/07/ ua_dnieper_river_basin_screeningfinalreport-eng.pdf.
- Barlow PM, Leake SA. Streamflow depletion by wells—Understanding and managing the effects of groundwater pumping on streamflow. USGS Circular 1376. Reston (VA): U.S. Geological Survey; 2012. 84 p. Available from: https://pubs.usgs.gov/circ/1376.
- Bazaluk O, Petlovanyi M, Sai K, Chebanov M, Lozynskyi V. Comprehensive assessment of the earth’s surface state disturbed by mining and ways to improve the situation: case study of Kryvyi Rih Iron-ore Basin, Ukraine. Front Environ Sci. 2024;12:1480344. DOI: 10.3389/fenvs.2024.1480344.
- Ministerstvo zakhystu dovkillya ta pryrodnykh resursiv Ukrayiny. Yedynyy reyestr z OVD: sprava № 20214137683 — «Nove budivnytstvo khvostoskhovyshcha “III karta” PAT “ArselorMittal Kryvyy Rih”» (Povidomlennya 16.04.2021; Zvit 07.07.2021) Kyyiv: Ministerstvo zakhystu dovkillya ta pryrodnykh resursiv Ukrayiny; 2021. Dostupno: https://eia.menr.gov.ua/. [in Ukrainian].
- Mosai AK, Ndlovu G, Tutu H. Improving acid mine drainage treatment by combining treatment technologies: A review. Sci Total Environ. 2024;919:170806. DOI: 10.1016/j.scitotenv.2024.170806.
- Wang Y, Cao J, Biswas A, Fang W, Chen L. Acid mine wastewater treatment: A scientometrics review. J Water Process Eng. 2024;57:104713. DOI: 10.1016/j.jwpe.2023.104713.
- Instytut telekomunikatsiy i hlobalnoho informatsiynoho prostoru NAN Ukrayiny. Doslidzhennya ekolohichnoho stanu terytoriy u fazi postmayninhu: teoriya, metodolohiya, keysy. Kyyiv: Instytut telekomunikatsiy i hlobalnoho informatsiynoho prostoru NAN Ukrayiny; 2021. 196 s. Dostupno: https://itgip.org/. [in Ukrainian].
- Kovalchuk PI, Sakhnenko VO, Sorokina OV. Balance method of integrated management of wastewater discharge by volume and mineralization of mine water in the Inhulets River basin. Melioration and Water Management. 2021;(1):23-32. DOI: 10.31073/mivg202101-274.
- Beliakevych IL. Hidroekolohichnyy analiz vplyvu diyalnosti hirnycho-zbahachuvalnykh pidpryyemstv Kirovohradskoyi oblasti na baseyn richky Inhulets [dyssertatsiia]. Bila Tserkva: Bila Tserkva National Agrarian University; 2023. 72 s. Dostupno: https://rep.btsau.edu.ua/bitstream/BNAU/ 12635/1/Белякевич%20.pdf. [in Ukrainian].
- U.S. Environmental Protection Agency. National recommended water quality criteria – Aquatic life criteria table. Washington (DC): US EPA; 2025. Available from: https://www.epa.gov/wqc/national-recommended-water-quality-criteria-aquatic-life-criteria-table.
- U.S. Environmental Protection Agency. Ambient water quality criteria for chloride – 1988. EPA 440/5-88-001. Washington (DC): US EPA; 1988. Available from: https://www.epa.gov/sites/default/files/2018-08/documents/ chloride-aquatic-life-criteria-1988.pdf.
- Harvey JW, Conaway CH, Dornblaser MM, Gellis AC, Stewart AR, Green CT, editors. Knowledge gaps and opportunities in water-quality drivers of aquatic ecosystem health. U.S. Geological Survey Open-File Report 2023-1085. Reston (VA): USGS; 2024. 72 p. DOI: 10.3133/ofr20231085.
- Ministerstvo okhorony zdorovya Ukrayiny. Nakaz № 721 Pro zatverdzhennya Hihiyenichnykh normatyviv yakosti vody vodnykh obyektiv dlya zadovolennya pytnykh, hospodarsko-pobutovykh ta inshykh potreb naselennya. Kyyiv: MOZ Ukrayiny; 2022. Dostupno: . [in Ukrainian].
Publication of the article:
«Bulletin of problems biology and medicine», 2025 Issue 4, 179, 94-105 pages, index UDC 504.5:546.3 (477.74)